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Colloidal Crystal Growth at Externally Imposed Nucleation Clusters

by: Sven van Teeffelen, Christos N Likos, Hartmut Löwen
Physical Review Letters, Vol. 100, No. 10. (2008)


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We study the conditions under which and how an imposed cluster of fixed colloidal particles at prescribed positions triggers crystal nucleation from a metastable colloidal fluid. Dynamical density functional theory of freezing and Brownian dynamics simulations are applied to a two-dimensional colloidal system with dipolar interactions. The externally imposed nucleation clusters involve colloidal particles either on a rhombic lattice or along two linear arrays separated by a gap. Crystal growth occurs after the peaks of the nucleation cluster have first relaxed to a cutout of the stable bulk crystal.


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